|
|
benzoylformate + CoA + NAD+ <=> benzoyl-CoA + CO2 + NADH
|
1.2.1.58
phenylglyoxylate dehydrogenase (acylating)
1.2.4.1
pyruvate dehydrogenase (acetyl-transferring)
|
–
–
|
K
|
|
BRENDA:
BR1124
KEGG:
R02450
MetaCyc:
1.2.1.58-RXN
|
|
|
|
benzoylformate + H+ <=> CO2 + benzaldehyde
|
4.1.1.1
pyruvate decarboxylase
4.1.1.7
benzoylformate decarboxylase
4.1.1.72
branched-chain-2-oxoacid decarboxylase
4.1.1.74
indolepyruvate decarboxylase
|
–
–
–
–
|
MK
|
|
BRENDA:
BR331
KEGG:
R01764
MetaCyc:
BENZOYLFORMATE-DECARBOXYLASE-RXN
SABIO-RK:
1863
|
|
|
|
phenylglyoxylyl-CoA + H2O <=> benzoylformate + H+ + CoA
|
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
|
MK
|
|
BRENDA:
BR48149
KEGG:
R07294
MetaCyc:
3.1.2.25-RXN
|
|
|
|
(S)-Mandelate + acceptor <=> benzoylformate + reduced_acceptor
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
1.1.99.31
(S)-mandelate dehydrogenase
1.1.99.B9
|
–
–
–
|
M
|
|
BRENDA:
BR48767
KEGG:
R03793
MetaCyc:
MANDELATE-DEHYDROGENASE-RXN
SABIO-RK:
3551
|
|
|
|
(R)-mandelate + NAD+ <=> benzoylformate + NADH + H+
|
1.1.1.272
D-2-hydroxyacid dehydrogenase (NADP+)
1.1.1.379
(R)-mandelate dehydrogenase
|
–
–
|
|
|
BRENDA:
BR51164
KEGG:
R03790
MetaCyc:
RXN-15840
SABIO-RK:
3548
|
|
|
|
(S)-Mandelate + FMN <=> benzoylformate + FMNH2
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
K
|
|
BRENDA:
BS438036
KEGG:
R07664
SABIO-RK:
6623
|
|
|
|
(S)-Mandelate + O2 <=> benzoylformate + H2O2
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
1.1.99.31
(S)-mandelate dehydrogenase
|
–
–
|
|
|
BRENDA:
BS383498
SABIO-RK:
8029
|
|
|
|
benzoylformate + NADH + H+ <=> Mandelate + NAD+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.345
D-2-hydroxyacid dehydrogenase (NAD+)
|
–
–
|
|
|
BRENDA:
BS398107
SABIO-RK:
9898
|
|
|
|
(S)-Mandelate + NAD+ <=> benzoylformate + NADH + H+
|
1.1.1
|
–
|
|
|
KEGG:
R03792
|
|
|
|
benzoylformate + CoA + acceptor + H+ <=> benzoyl-CoA + CO2 + reduced_acceptor
|
1.2
|
–
|
M
|
|
MetaCyc:
PHENGLYOXRED-RXN
|
|
|
|
2-oxoglutarate + D-phenylglycine <=> L-glutamate + benzoylformate
|
2.6.1.72
D-4-hydroxyphenylglycine transaminase
|
–
|
M
|
|
MetaCyc:
RXN-21531
|
|
|
|
phenylacetyl-CoA + O2 <=> benzoylformate + CoA
|
1.13.11.80
(3,5-dihydroxyphenyl)acetyl-CoA 1,2-dioxygenase
|
–
|
|
|
BRENDA:
BS430593
|
|
|
|
benzoylformate + FAD + CoA <=> benzoyl-CoA + CO2 + FADH2
|
1.2.1.58
phenylglyoxylate dehydrogenase (acylating)
|
–
|
|
|
BRENDA:
BS5616
|
|
|
|
D-phenylglycine + H2O + O2 <=> benzoylformate + NH3 + H2O2
|
1.4.3.3
D-amino-acid oxidase
|
–
|
|
|
BRENDA:
BS396925
|
|
|
|
phenylglycine + H2O + O2 <=> benzoylformate + NH3 + H2O2
|
1.4.3.3
D-amino-acid oxidase
|
–
|
|
|
BRENDA:
BS259067
|
|
|
|
benzoylformate + CoA + oxidized_ferredoxin <=> benzoyl-CoA + CO2 + reduced_ferredoxin
|
1.2.7.7
3-methyl-2-oxobutanoate dehydrogenase (ferredoxin)
|
–
|
|
|
BRENDA:
BS359421
|
|
|
|
benzoylformate + Oxidized_benzyl_viologen + CoA <=> benzoyl-CoA + CO2 + reduced_benzyl_viologen
|
1.2.1.58
phenylglyoxylate dehydrogenase (acylating)
|
–
|
|
|
BRENDA:
BS5614
|
|
|
|
benzoylformate + FMN + CoA <=> benzoyl-CoA + CO2 + FMNH2
|
1.2.1.58
phenylglyoxylate dehydrogenase (acylating)
|
–
|
|
|
BRENDA:
BS5617
|
|
|
|
benzoylformate + methyl_viologen + CoA <=> benzoyl-CoA + CO2 + reduced_methyl_viologen
|
1.2.1.58
phenylglyoxylate dehydrogenase (acylating)
|
–
|
|
|
BRENDA:
BS5615
|
|
|
|
Mandelate + O2 <=> benzoylformate + H2O2
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
|
–
|
|
|
BRENDA:
BS405026
|
|
|
|
Mandelate + 2,6-dichlorophenolindophenol <=> benzoylformate + reduced_2,6-dichlorophenolindophenol
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
1.1.99.31
(S)-mandelate dehydrogenase
|
–
–
|
|
|
BRENDA:
BS257446
|
|
|
|
(S)-Mandelate + 2,6-dichlorophenolindophenol <=> benzoylformate + reduced_2,6-dichlorophenolindophenol
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
1.1.99.31
(S)-mandelate dehydrogenase
|
–
–
|
|
|
BRENDA:
BS257445
|
|
|
|
Mandelate + ferricyanide <=> benzoylformate + ferrocyanide + H2O
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
|
|
BRENDA:
BS384626
|
|
|
|
Phenylglyoxal + ferricyanide <=> benzoylformate + ferrocyanide + H+
|
1.2.5.2
aldehyde dehydrogenase (quinone)
|
–
|
|
|
BRENDA:
BS432291
|
|
|
|
(S)-Mandelate + 2 ferricyanide <=> benzoylformate + 2 ferrocyanide + 2 H+
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
|
|
BRENDA:
BS383519
|
|
|
|
L-glutamate + benzoylformate <=> L-phenylglycine + 2-oxoglutarate
|
2.6.1.57
aromatic-amino-acid transaminase
|
–
|
|
|
BRENDA:
BS389033
|
|
|
|
benzoylformate + NH3 + NADH + H+ <=> L-2-aminophenylacetic_acid + H2O + NAD+
|
1.4.1.9
leucine dehydrogenase
|
–
|
|
|
BRENDA:
BS440701
|
|
|
|
(S)-Mandelate + O2 <=> benzoylformate
|
1.1.3.46
4-hydroxymandelate oxidase
|
–
|
|
|
BRENDA:
BS425212
|
|
|
|
benzoylformate <=> (R)-benzoin
|
4.1.1.7
benzoylformate decarboxylase
|
–
|
|
|
BRENDA:
BS1586
|
|
|
|
benzoylformate + reduced_benzyl_viologen <=> (R)-mandelate
|
1.1.99.30
2-oxo-acid reductase
|
–
|
|
|
BRENDA:
BS374307
|
|
|
|
benzoylformate + reduced_methyl_viologen <=> (R)-mandelate
|
1.1.99.30
2-oxo-acid reductase
|
–
|
|
|
BRENDA:
BS374308
|
|
|
|
benzoylformate + NADPH + H+ <=> Mandelate + NADP+
|
1.1.1.1
alcohol dehydrogenase
|
–
|
|
|
BRENDA:
BS396576
|
|
|
|
(R)-mandelate + NADP+ <=> benzoylformate + NADPH + H+
|
1.1.1.B65
|
–
|
|
|
BRENDA:
BS440452
|
|
|
|
Mandelate + oxidized_acceptor <=> benzoylformate + reduced_acceptor
|
1.1.99.30
2-oxo-acid reductase
|
–
|
|
|
BRENDA:
BS373787
|
|
|
|
Mandelate + acceptor <=> benzoylformate + reduced_acceptor
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
|
|
BRENDA:
BS385124
|
|
|
|
benzoylformate + acetaldehyde <=> (S)-2-Hydroxypropiophenone
|
4.1.1.7
benzoylformate decarboxylase
|
–
|
|
|
BRENDA:
BS1587
|
|
|
|
benzoylformate + L-tyrosine <=> L-phenylalanine + 4-hydroxyphenylpyruvate
|
2.6.1.B17
|
–
|
|
|
BRENDA:
BS437207
|
|
|
|
benzoylformate + L-phenylalanine <=> L-phenylglycine + phenylpyruvate
|
2.6.1.B17
|
–
|
|
|
BRENDA:
BS437821
|
|
|
|
phenylpyruvate + phenylglycine <=> L-phenylalanine + benzoylformate
|
2.6.1.28
tryptophan---phenylpyruvate transaminase
|
–
|
|
|
BRENDA:
BS356442
|
|
|
|
Mandelate + FMN <=> benzoylformate + FMNH2
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
|
|
SABIO-RK:
6584
|
|
|
|
NADP+ + Phenylglyoxal + H2O <=> NADPH + benzoylformate + H+
|
1.2.1.49
2-oxoaldehyde dehydrogenase (NADP+)
|
–
|
|
|
SABIO-RK:
10040
|
|
|
|
H2O + Phenylglyoxal + NAD+ <=> H+ + benzoylformate + NADH
|
1.2.1.23
2-oxoaldehyde dehydrogenase (NAD+)
|
–
|
|
|
SABIO-RK:
10036
|
|